December 2008

Journal

Charge Order, Dynamics, and Magnetostructural Transition in Multiferroic LuFe2O4

By:
Xu, S. U.; Angst, Niklaus M; Brinzari, T. V.; Hermann, Raphael; Musfeldt, J.; Christianson, Andrew D; Mandrus, David ; Mcgill, S.; Kim, Jong-Woo; Islam, Z.
Journal Name:
Physical Review Letters
Page Number:
227602
Volume:
101
Issue Number:
22
Publication Date:
December 8, 2008
View DOI Listing:
https://doi.org/10.1103/PhysRevLett.101.227602

Abstract

The cascade of temperature and field-driven transitions in LuFeO was investigated byM�Nossbauer and optical spectroscopies, magnetization, and x-ray scattering. A correlation of Fe2+ ��Fe3+ charge transfer excitations with the 320 K phase transition below which uperstructure reflections appear confirms its association with gradual charge carrier freezing. Fe2+ on-site excitations are sensitive to the 175 K magnetic transition, which Bragg splitting and large magneto optical contrast suggest involes a monoclinic distortion that can be driven by both temperature and magnetic field. PACS numbers: 71.30.+h,75.30.Kz,78.20.Ci,76.70.+y


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