Publications

Showing 124 results for Author: Bruce A. Moyer

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Aug, 2026

Journal

An Application of Molecular Recognition for the Efficient Removal of Cesium from Hanford Nuclear Waste by Modular Solvent Extraction

In this work, experimental results leading to flowsheet design are presented showing how a calixarene-crown ether based solvent-extraction process can meet the challenge of cesium removal from nuclear tank wastes stored at the US Department of Energy Hanford site. Cleanup of legacy Cold War nuclear waste stored in underground tanks represents one of the greatest environmen…
Apr, 2026

Journal

Efficient Low-Temperature Direct Lithium Extraction from Chloride Brines Enabled by High-Capacity Sorbent

The demand for lithium, a key component in rechargeable batteries for electric vehicles and renewable energy storage systems, has surged in recent years. Meeting this demand requires efficient extraction methods that are both environmentally friendly and economically viable. This study investigates the utilization of the high-capacity sorbent amorphous aluminum hydroxide f…
Feb, 2026

Journal

Capture of Volatile RuO4 from Oxidized Simulated Used Nuclear Fuel Solutions

Ruthenium is a challenging fission product in used nuclear fuel (UNF) reprocessing due to its complex redox chemistry, variable speciation in nitric acid, partial extractability, and volatility. This work presents a strategy for Ru removal based on the volatilization of RuO4 using the strong oxidant sodium bismuthate, followed by RuO2 deposition onto various substrates. Am…
Jan, 2026

Journal

Recovering High-Purity Uranyl Nitrate from Simulated Used Nuclear Fuel Dissolver Solutions by Crystallization: Rejecting Technetium

The separation of U from Tc and other problematic fission product elements like Mo and Ru, along with Sr, Zr, Cs, and Nd, has been achieved via the crystallization of uranyl nitrate hexahydrate (UNH). Rejection of technetium as pertechnetate anion (99TcO4–) is an especially important feature of this system, as it otherwise tends to follow U(VI) in extractive separations. I…
Nov, 2025

Journal

New directions and principles for solvent extraction for recovery of lithium from aqueous brines and mineral leachates: A brief review

Increasing demand for lithium for manufacturing of batteries is fueling the unprecedented search for improved recovery and alternative sources. Wider source distribution, lower energy consumption, and greater sustainability make extraction of lithium from brines, both natural and process-derived, an attractive alternative to mineral ores. Solvent extraction, used industria…
Nov, 2024

Journal

A New Triketone Ligand for Extraction of Lithium from Brines

Recovery of lithium from brines by liquid-liquid solvent extraction (LLE) with diketones and synergistic co-ligands has been investigated for decades, but industrial application has been limited. In pursuit of a ligand with improved properties, a series of ketonamides with beta-carbonyl groups were designed, synthesized, and tested in extraction of lithium from sulfate and…
Sep, 2024

Journal

Integrated Circular Economy Model System for Direct Lithium Extraction: From Minerals to Batteries Utilizing Aluminum Hydroxide

Aluminum hydroxide, an abundant mineral found in nature, exists in four polymorphs: gibbsite, bayerite, nordstrandite, and doyleite. Among these polymorphs gibbsite, bayerite, and commercially synthesized amorphous aluminum hydroxide have been investigated as sorbent materials for lithium extraction from sulfate solutions. The amorphous form of Al(OH)3 exhibits a reactivit…
Jun, 2024

Conference Paper

Solvent Extraction System Modeling Using the Program SXFIT

SXFIT is the latest in a series of programs developed in our group to model solvent extraction systems of increasing complexity. SXFIT permits the user complete freedom to define the constituents from which the composition of each phase is to be specified in the data and from which all species of a model for a system are assumed to be formed. Activity coefficients in the n…
Jan, 2024

Journal

Integrated Circular Economy Model System for Direct Lithium Extraction: From Minerals to Batteries Utilizing Aluminum Hydroxide

Aluminum hydroxide, an abundant mineral found in nature, exists in four polymorphs: gibbsite, bayerite, nordstrandite, and doyleite. Among these polymorphs gibbsite, bayerite, and commercially synthesized amorphous aluminum hydroxide have been investigated as sorbent materials for lithium extraction from sulfate solutions. The amorphous form of Al(OH)3 exhibits a reactivit…
Dec, 2023

Journal

Lithium Recovery from Aqueous Resources and Batteries: A Brief Review

The demand for lithium is expected to increase drastically in the near future due to the increased usage of rechargeable lithium-ion batteries (LIB) in electric vehicles, smartphones and other portable electronics. To alleviate the potential risk of undersupply, lithium can be extracted from raw sources consisting of minerals and brines or from recycled batteries and glass…
Dec, 2023

Journal

Lithium aluminum‐layered double hydroxide chlorides (LDH): Formation enthalpies and energetics for lithium ion capture

Layered aluminum double hydroxide chloride sorbents, LiCl∙Al2(OH)6.nH2O, Li‐LDH, have shown promising application in selective Li extraction from geothermal brines. Maintaining LiCl uptake capacity and retaining a long cycle life are critical to widespread application of sorbent materials. To elucidate the energetics of Li capture, enthalpies of LDH with different Li conte…
Dec, 2023

Journal

Enhancing selectivity of cation exchange with anion receptors

We introduce a new supramolecular strategy where an anion receptor modifies the selectivity ligands for cations. This is demonstrated by combining the classic anion receptor calix[4]pyrrole (C4P) and a phenolic ligand, which leads to remarkable enhancement in selectivity for Cs+ over Na+. Crystal structures and molecular simulations confirmed the persistent formation of io…

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Publications

An Application of Molecular Recognition for the Efficient Removal of Cesium from Hanford Nuclear Waste by Modular Solvent Extraction

Efficient Low-Temperature Direct Lithium Extraction from Chloride Brines Enabled by High-Capacity Sorbent

Capture of Volatile RuO4 from Oxidized Simulated Used Nuclear Fuel Solutions

Recovering High-Purity Uranyl Nitrate from Simulated Used Nuclear Fuel Dissolver Solutions by Crystallization: Rejecting Technetium

New directions and principles for solvent extraction for recovery of lithium from aqueous brines and mineral leachates: A brief review

A New Triketone Ligand for Extraction of Lithium from Brines

Integrated Circular Economy Model System for Direct Lithium Extraction: From Minerals to Batteries Utilizing Aluminum Hydroxide

Solvent Extraction System Modeling Using the Program SXFIT

Integrated Circular Economy Model System for Direct Lithium Extraction: From Minerals to Batteries Utilizing Aluminum Hydroxide

Lithium Recovery from Aqueous Resources and Batteries: A Brief Review

Lithium aluminum‐layered double hydroxide chlorides (LDH): Formation enthalpies and energetics for lithium ion capture

Enhancing selectivity of cation exchange with anion receptors