November 2011

Conference Paper

Characterization of durable nanostructured thin film catalysts tested under transient conditions using analytical aberration-corrected electron microscopy

By:
Cullen, David A; More, Karren L; Reeves, Kimberly S; Vernstrom, George; Atanasoska, Liliana; Haugen, Gregory; Atanasoski, Radoslav
Publication Date:
November 10, 2011
Conference Name:
220th ECS Meeting and Electrochemical Energy Summit
Conference Location:
Boston, Massachusetts, United States of America

Abstract

The stability of Ru0.1Ir0.9 oxidation evolution reaction (OER) catalysts deposited on Pt-coated nanostructured thin films (NSTFs) has been investigated by aberration-corrected electron microscopy. Accelerated stress tests showed that the OER catalysts significantly improved the durability of the Pt under cell reversal conditions. High-resolution images of the end-of-life NSTFs showed significant Ir loss from the whisker surfaces, while no Pt loss was observed, indicating that the OER catalysts had protected the catalyst coated whisker surfaces from degradation.