- By:
- Pajerowski, Daniel M; Manson, Jamie L; Herbrych, Jacek W; Meisel, Mark; Bendix, Jesper; Podlesnyak, Andrey A; Cain, John M
- Journal Name:
- Physical Review B
- Page Number:
- 94431
- Volume:
- 101
- Issue Number:
- 9
- Publication Date:
- November 9, 2023
- View DOI Listing:
- https://doi.org/10.1103/PhysRevB.101.094431
Abstract
[Ni(HF2)(3−Clpyridine)4]BF4 (NBCT) is a one-dimensional, S=1 spin chain material that shows no magnetic neutron Bragg peaks down to temperatures of 0.1 K. Previous work identified NBCT as being in the Haldane phase and near a quantum phase transition as a function of D/J to the large-D quantum paramagnet phase (QPM), where D is the axial single-ion anisotropy and J is the intrachain superexchange. Herein, inelastic neutron scattering results are presented on partially deuterated, 11B-enriched NBCT polycrystalline samples in zero magnetic field and down to temperatures of 0.3 K. Comparison to density matrix renormalization group calculations yields D/J=1.51 and a significant rhombic single-ion anisotropy E (E/D≈0.03, E/J≈0.05). These D, J, and E values place NBCT in the large-D QPM phase but precipitously near a quantum phase transition to a long-range ordered phase.
