- By:
- Sun, Xiao-Guang ; Wan, Shun ; Guan, Hongyu ; Fang, Youxing ; Reeves, Kimberly S; Chi, Miaofang ; Dai, Sheng
- Journal Name:
- Journal of Materials Chemistry A
- Page Number:
- 1233-1241
- Volume:
- 5
- Issue Number:
- 3
- Publication Date:
- February 14, 2017
- View DOI Listing:
- https://doi.org/10.1039/c6ta07757a
Abstract
Three new lithium salts, lithium difluoro-2-methyl-2-fluoromalonaoborate (LiDFMFMB), lithium difluoro-2-ethyl-2-fluoromalonaoborate (LiDFEFMB), and lithium difluoro-2-propyl-2-fluoro malonaoborate (LiDFPFMB), have been synthesized and evaluated for application in lithium ion batteries. These new salts are soluble in a mixture of ethylene carbonate (EC) and ethyl methyl carbonate (EMC) (1:2 by wt.) and 1.0 M salt solutions can be easily prepared. The ionic conductivities of these new salts are close to those of LiBF4 and LiPF6. Cyclic voltammograms reveal that these new salt based electrolytes can passivate both natural graphite and high voltage spinel LiNi0.5Mn1.5O4 (LNMO) to form effective solid electrolyte interphases (SEIs). In addition, these new salts based electrolytes exhibit good cycling stability with high coulombic efficiencies in both LiNi0.5Mn1.5O4 and graphite based half-cells and full cells.
