August 2026

Journal

Porous reaction-bonded silicon nitride: Size effects for pressureless nitriding of binder jet additively manufactured silicon

By:
Aguirre, Trevor G; Cakmak, Ercan ; Richardson, Michael D; Curlin, Stephanie M; Martinez, Marco C; Lance, Michael J; Wang, Hsin ; Cramer, Corson L; Bullock, Steve E; Armstrong, Beth L
Journal Name:
npj Advanced Manufacturing
Page Number:
2
Volume:
TBD
Publication Date:
August 17, 2026
View DOI Listing:
https://doi.org/10.1038/s44334-026-00110-y

Abstract

The direct nitridation of binder jet additively manufactured silicon to produce porous reaction-bonded silicon nitride was explored to determine the maximum thickness of the sample that could be converted to >99% silicon nitride. The maximum thickness that could be nitrided was investigated by nitriding cubes of increasing physical size on the millimeter scale. Highly porous samples with high conversion ( > 99%) to silicon nitride were achieved in cubes with 35 mm edge length. It was shown that the silicon nitride phase content changes with increasing sample size.